TpOx-Ph-p-OMe

TpOx-Ph-p-OMe is a UV excitable fluorescent material with a polycyclic aromatic donor-acceptor structure where the triphenoxazole core acts as a donor and the aromatic group on the two position of the oxazole (4-methoxy-phenyl) act as the acceptor group. The push-pull, donor-acceptor, structure facilitates intramolecular charge transfer in the excited state that results in a 170 nm emission Stokes Shift. TpOx-Ph-p-OMe is also a photo-conducting Discotic Liquid Crystalline (DLC) material with mesophase transition onset temperature of 115°C. TpOx-Ph-p-OMe is designed for 355 nm excitation with emission at 440 nm with quantum yield of 0.4, high thermal, chemical and photostability. TpOx-Ph-p-OMe has potential uses in fluorescent dye staining, organic electronic and photonics, and imaging applications.

TpOx-Ph-p-OMe can be purchased from Sigma Aldrich website.

Please contact us for more information.

 

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The TpOx-Ph-p-OMe properties (In EtOAc Solvent):

  • Abs λmax  = 270 nm
  • ϵ at Abs λmax = 97,000 M-1 cm-1
  • ϵ at Abs λ355 = 21,700 M-1 cm-1
  • Emis λmax = 440 nm
  • pSS = 170 nm
  • Quantum Yield (Φ) = 0.4

 

Discotic Liquid Crystal Phase transition temperature:

  • Heating: Crys – Colh 115°C, Colh – Iso 186°C

 

Solubility:

  • THF > 1 mg /mL
  • DCM > 1 mg /mL
  • MeCN < 0.17 mg / mL
  • DMSO < 0.2 mg / mL